Oxidation of C-H Bonds
-15%
portes grátis
Oxidation of C-H Bonds
;
John Wiley and Sons Ltd
04/2017
528
Dura
Inglês
9781119092520
15 a 20 dias
Descrição não disponível.
Preface xi 1 Introduction 1 1.1 What Is Oxidation of C H Bonds? 1 1.2 Chemical Synthesis and Oxidation of C H Bonds 2 1.3 C H Bonds 6 1.4 Concepts in This Book 15 References 17 2 Oxidation of Methane 19 2.1 Methane 19 2.2 Methyl sp^3 C H Bond 20 2.3 Oxidations of Methyl sp^3 C H Bond 21 2.4 Summary 35 References 36 3 Oxidation of Alkyl sp^3 C H Bond 39 3.1 Alkane 39 3.2 Alkyl sp^3 C H Bonds 40 3.3 Oxidations of Alkyl sp^3 C H Bond 42 3.4 Summary 61 References 62 4 Oxidation of Alkyl sp^3 C H Bond Assisted by Directing Group 65 4.1 Directing Group 65 4.2 Alkyl sp^3 C H Bonds with Directing Groups 66 4.3 Directed Oxidations of Alkyl sp^3 C H Bond 67 4.4 Summary 97 References 97 5 Oxidation of Alkyl sp^3 C H Bond Adjacent to Unsaturated Carbon Atom 101 5.1 Alkyl -sp^3 C H Bond 101 5.2 Alkyl sp^3 C H Bonds Adjacent to Unsaturated Carbon Atoms 102 5.3 Oxidations of Alkyl sp^3 C H Bond Adjacent to Unsaturated Carbon Atom 103 5.4 Summary 138 References 138 6 Oxidation of Alkyl sp^3 C H Bond Adjacent to Heteroatom 143 6.1 Alkyl sp^3 C H Bonds Adjacent to Heteroatoms 143 6.2 Oxidations of Alkyl sp^3 C H Bond Adjacent to Heteroatom 144 6.3 Summary 166 References 167 7 Oxidation of Alkenyl or Carbonyl sp^2 C H Bond 171 7.1 Alkenyl and Carbonyl sp^2 C H Bonds 171 7.2 Oxidations of Alkenyl and Carbonyl sp^2 C H Bonds 172 8 Oxidation of Alkynyl spC H Bond 209 8.1 spC H Bonds 209 8.2 Oxidations of spC H Bond 210 8.3 Summary 232 References 232 9 Oxidation of Benzene 235 9.1 Introduction 235 9.2 Oxidations of Phenyl sp2 C H Bond 237 9.3 Summary 277 References 279 10 Oxidation of Aryl sp^2 C H Bond on Substituted Benzene 283 10.1 Introduction 283 10.2 Formation of C C Bond 284 10.3 Formation of C N Bond 313 10.4 Formation of C O Bond 316 10.5 Formation of C S Bond 322 10.6 Formation of C Halogen Bond 323 10.7 Summary 331 References 333 11 Oxidation of Aryl sp^2 C H Bond Assisted by Directing Group 337 11.1 Introduction 337 11.2 Formation of C C Bond 337 11.3 Formation of C N Bond 400 11.4 Formation of C O Bond 406 11.5 Formation of C S Bond 412 11.6 Formation of C Halogen Bond 414 11.7 Summary 424 References 426 12 Oxidation of Aryl sp^2 C H Bond on Heteroarene or Perfluoroarene 433 12.1 Introduction 433 12.2 Formation of C C Bond 434 12.3 Formation of C N Bond 459 12.4 Formation of C O Bond 461 12.5 Formation of C Halogen Bond 462 12.6 Cross -Coupling of Dual Aryl sp^2 C H Bonds on Directing -Group -Containing Arenes, Heteroarenes, or Polyfluoroarenes 468 12.7 Summary 477 References 478 13 Oxidative Cross -Coupling of Aryl sp^2 C H Bond with Inert C H Bond 483 13.1 Introduction 483 13.2 Oxidative Coupling of Simple Arenes with Alkanes (Alkylation of Arenes) 484 13.3 Oxidative Coupling of Simple Arenes with Alkenes (Alkenylation of Arenes) 486 13.4 Oxidative Cross -Coupling of Simple Arenes (Arylation of Arenes) 490 13.5 Summary 498 References 499 Index 501
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Preface xi 1 Introduction 1 1.1 What Is Oxidation of C H Bonds? 1 1.2 Chemical Synthesis and Oxidation of C H Bonds 2 1.3 C H Bonds 6 1.4 Concepts in This Book 15 References 17 2 Oxidation of Methane 19 2.1 Methane 19 2.2 Methyl sp^3 C H Bond 20 2.3 Oxidations of Methyl sp^3 C H Bond 21 2.4 Summary 35 References 36 3 Oxidation of Alkyl sp^3 C H Bond 39 3.1 Alkane 39 3.2 Alkyl sp^3 C H Bonds 40 3.3 Oxidations of Alkyl sp^3 C H Bond 42 3.4 Summary 61 References 62 4 Oxidation of Alkyl sp^3 C H Bond Assisted by Directing Group 65 4.1 Directing Group 65 4.2 Alkyl sp^3 C H Bonds with Directing Groups 66 4.3 Directed Oxidations of Alkyl sp^3 C H Bond 67 4.4 Summary 97 References 97 5 Oxidation of Alkyl sp^3 C H Bond Adjacent to Unsaturated Carbon Atom 101 5.1 Alkyl -sp^3 C H Bond 101 5.2 Alkyl sp^3 C H Bonds Adjacent to Unsaturated Carbon Atoms 102 5.3 Oxidations of Alkyl sp^3 C H Bond Adjacent to Unsaturated Carbon Atom 103 5.4 Summary 138 References 138 6 Oxidation of Alkyl sp^3 C H Bond Adjacent to Heteroatom 143 6.1 Alkyl sp^3 C H Bonds Adjacent to Heteroatoms 143 6.2 Oxidations of Alkyl sp^3 C H Bond Adjacent to Heteroatom 144 6.3 Summary 166 References 167 7 Oxidation of Alkenyl or Carbonyl sp^2 C H Bond 171 7.1 Alkenyl and Carbonyl sp^2 C H Bonds 171 7.2 Oxidations of Alkenyl and Carbonyl sp^2 C H Bonds 172 8 Oxidation of Alkynyl spC H Bond 209 8.1 spC H Bonds 209 8.2 Oxidations of spC H Bond 210 8.3 Summary 232 References 232 9 Oxidation of Benzene 235 9.1 Introduction 235 9.2 Oxidations of Phenyl sp2 C H Bond 237 9.3 Summary 277 References 279 10 Oxidation of Aryl sp^2 C H Bond on Substituted Benzene 283 10.1 Introduction 283 10.2 Formation of C C Bond 284 10.3 Formation of C N Bond 313 10.4 Formation of C O Bond 316 10.5 Formation of C S Bond 322 10.6 Formation of C Halogen Bond 323 10.7 Summary 331 References 333 11 Oxidation of Aryl sp^2 C H Bond Assisted by Directing Group 337 11.1 Introduction 337 11.2 Formation of C C Bond 337 11.3 Formation of C N Bond 400 11.4 Formation of C O Bond 406 11.5 Formation of C S Bond 412 11.6 Formation of C Halogen Bond 414 11.7 Summary 424 References 426 12 Oxidation of Aryl sp^2 C H Bond on Heteroarene or Perfluoroarene 433 12.1 Introduction 433 12.2 Formation of C C Bond 434 12.3 Formation of C N Bond 459 12.4 Formation of C O Bond 461 12.5 Formation of C Halogen Bond 462 12.6 Cross -Coupling of Dual Aryl sp^2 C H Bonds on Directing -Group -Containing Arenes, Heteroarenes, or Polyfluoroarenes 468 12.7 Summary 477 References 478 13 Oxidative Cross -Coupling of Aryl sp^2 C H Bond with Inert C H Bond 483 13.1 Introduction 483 13.2 Oxidative Coupling of Simple Arenes with Alkanes (Alkylation of Arenes) 484 13.3 Oxidative Coupling of Simple Arenes with Alkenes (Alkenylation of Arenes) 486 13.4 Oxidative Cross -Coupling of Simple Arenes (Arylation of Arenes) 490 13.5 Summary 498 References 499 Index 501
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