Novel Nanoscale Hybrid Materials
-15%
portes grátis
Novel Nanoscale Hybrid Materials
John Wiley and Sons Ltd
04/2018
368
Dura
Inglês
9781119156246
15 a 20 dias
Descrição não disponível.
List of Contributors xiii 1 Silanols as Building Blocks for Nanomaterials 1 Masafumi Unno and Hisayuki Endo 1.1 Introduction 1 1.2 Synthesis and Applications of Silanols 2 1.2.1 Silanetriols and Disiloxanetetraols 2 1.2.2 Cyclotetrasiloxanetetraol (Cyclic Silanols, All ]cis Isomer) 5 1.2.3 Cyclotetrasiloxanetetraol (Cyclic Silanols, Other Isomers) 14 1.2.4 Cyclotrisiloxanetriol 15 1.3 Structures and Properties of Nanomaterials Obtained from Silanols 20 1.3.1 Structure of Laddersiloxanes 20 1.3.2 Thermal Property of Laddersiloxanes 23 1.3.3 Thermal Property of Other Silsesquioxanes 26 1.3.4 Refractive Indices of Silsesquioxanes 28 1.4 Summary and Outlook 29 References 29 2 Biomacromolecule ]Enabled Synthesis of Inorganic Materials 33 Kristina L. Roth and Tijana Z. Grove 2.1 Introduction 33 2.2 DNA 34 2.3 Proteins and Peptides 36 2.3.1 Cage Proteins 37 2.3.2 Bovine Serum Albumin (BSA) 38 2.3.3 Engineered Peptides 40 2.3.4 Engineered Protein Scaffolds 42 2.4 Polysaccharides 44 2.5 Methods of Characterization 46 2.6 Conclusion 50 References 50 3 Multilayer Assemblies of Biopolymers: Synthesis, Properties, and Applications 57 Jun Chen, Veronika Kozlovskaya, Danielle Pretorius, and Eugenia Kharlampieva 3.1 Introduction 57 3.2 Assembly of Biopolymer Multilayers 58 3.2.1 Biopolymers and Their Properties 58 3.2.2 Growth and Thickness of Biopolymer Multilayers 59 3.2.3 Stability in Solutions and Enzymatic Degradation of Biopolymer Multilayers 74 3.2.3.1 Enzymatic Degradation 75 3.2.3.2 pH and Salt Stability 78 3.2.4 Hydration and Swelling of Biopolymer Multilayers 81 3.3 Properties of Biopolymer Multilayers 83 3.3.1 Surface Properties of Biopolymer Multilayers and Their Interaction with Cells 83 3.3.2 Antibacterial Properties 84 3.3.3 Immunomodulatory Properties 85 3.3.4 Mechanical Properties of Biopolymer Multilayers 87 3.3.5 Other Properties 90 3.4 Applications 91 3.5 Conclusion and Outlook 95 Acknowledgments 96 References 96 4 Functionalization of P3HT ]Based Hybrid Materials for Photovoltaic Applications 107 Michele Chevrier, Riccardo Di Ciuccio, Olivier Coulembier, Philippe Dubois, Sebastien Richeter, Ahmad Mehdi, and Sebastien Clement 4.1 Introduction 107 4.2 Design and Synthesis of Regioregular Poly(3 ]Hexylthiophene) 109 4.2.1 Metal ]Catalyzed Cross ]Coupling Reactions 114 4.2.1.1 Nickel ]Catalyzed Cross ]Coupling Reactions 114 4.2.1.2 Palladium ]Catalyzed Cross ]Coupling Reactions 121 4.2.2 Functionalization of P3HT 126 4.2.2.1 End ]Group Functionalization 127 4.2.2.2 Side ]Chain Functionalization 130 4.3 Morphology Control of P3HT/PCBM Blend by Functionalization 132 4.3.1 Introduction 132 4.3.2 End ]Group Functionalization 134 4.3.2.1 Fluorinated Chain Ends 135 4.3.2.2 Hydrophilic Chain Ends 139 4.3.2.3 Aromatic Chain Ends 139 4.3.2.4 Fullerene Chain Ends: Compatibilizer Case 141 4.3.3 Side ]Chain Functionalization 144 4.3.3.1 Thermal and Photo ]Cross ]Linking 144 4.3.3.2 Fullerene Side ]Functionalization on Polythiophene Block Copolymers 147 4.3.3.3 Cooperative Self ]Assembling 149 4.4 Polymer-Metal Oxide Hybrid Solar Cells 154 4.4.1 Anchoring Method 156 4.4.2 Surface Modification Using End ] and Side ]Chain ]Functionalized P3HT 158 4.4.2.1 End ]Group Functionalization 158 4.4.2.2 Side ]Chain Functionalization 161 4.5 Conclusion 163 Acknowledgments 164 References 164 5 Insights on Nanofiller Reinforced Polysiloxane Hybrids 179 Debarshi Dasgupta, Alok Sarkar, Dieter Wrobel, and Anubhav Saxena 5.1 Properties of Silicone (Polysiloxane) 179 5.2 Nanofiller Composition and Chemistry 183 5.2.1 Fumed Silica 183 5.2.2 Aerogel Silica 185 5.2.3 Carbon Black 187 5.3 Polymer [Poly(dimethylsiloxane)]-Filler Interaction 187 5.4 Polymer- Filler Versus Filler-Filler Interactions 190 5.5 PDMS Nanocomposite with Anisotropic Fillers 194 5.6 PDMS- Molecular Filler Nanocomposite 196 Acknowledgment 198 References 198 6 Nanophotonics with Hybrid Nanostructures: New Phenomena and New Possibilities 201 Noor Eldabagh, Jessica Czarnecki, and Jonathan J. Foley IV 6.1 Introduction 202 6.2 Theoretical Nanophotonics 204 6.2.1 Mie Theory for Spherical Nanostructures 205 6.2.2 Transfer Matrix Methods for Planar Structures 208 6.2.3 The Finite ]Difference Time ]Domain Method 214 6.2.4 The Discrete Dipole Approximation 215 6.3 Hybrid Nanostructures 216 6.3.1 Emergent Electrodynamics Phenomena: Inhomogeneous Surface Plasmon Polaritons 216 6.3.2 Advancing Imaging Beyond the Diffraction Limit with ISPPs 220 6.3.3 Emergent Material ]Dependent Optical Response in Hybrid Nanostructures 222 6.3.4 Perspective on the Horizon of Health Applications of Hybrid Nanostructures 228 6.3.5 Photodynamic Therapy 228 6.3.6 In Vivo Light Sources 231 6.4 Concluding Remarks 233 References 233 7 Drug Delivery Vehicles from Stimuli ]Responsive Block Copolymers 239 Prajakta Kulkarni and Sanku Mallik 7.1 Introduction 239 7.2 Block Copolymers for Drug Delivery 241 7.3 Polymeric Nanoparticles 241 7.3.1 Micelles 241 7.3.2 Hydrogels 243 7.3.3 Polymersomes 244 7.4 Stimuli ] Responsive Drug Delivery 245 7.4.1 Physical/External Stimuli ]Responsive Polymers 246 7.4.1.1 Temperature 246 7.4.1.2 Electro ]Responsive Polymers 247 7.4.1.3 Light ]Responsive Polymers 247 7.4.1.4 Ultrasound ]Responsive Polymers 248 7.4.2 Chemical/Internal Stimuli ]Responsive Polymers 248 7.4.2.1 PH ]Responsive Polymers 248 7.4.2.2 Ionic Strength ]Responsive Polymers 251 7.4.2.3 Enzyme ]Responsive Polymers 251 7.4.2.4 Reduction ]Sensitive Polymers 251 7.5 Challenges and Prospects 252 7.6 Summary 252 References 253 8 Mechanical Properties of Rubber ]Toughened Epoxy Nanocomposites 263 B. Zewde, I. J. Zvonkina, A. Bagasao, K. Cassimere, K. Holloway, A. Karim, and D. Raghavan 8.1 Introduction 263 8.2 Epoxy Resins 265 8.3 Rubber ] Toughened Epoxy Resin 266 8.4 Nanoparticle Filled Epoxy Nanocomposites 269 8.5 Carbon Nanotubes 270 8.6 Rubber ]Toughened CNT Filled Epoxy Nanocomposites 275 8.7 Nanoclay Filled Epoxy Nanocomposites 277 8.8 Rubber ]Toughened Nanoclay Filled Epoxy Nanocomposites 282 8.9 Silicon Dioxide Nanoparticles 284 8.10 Rubber ]Toughened Nanosilica Filled Epoxy Nanocomposites 286 8.11 Conclusions 289 Acknowledgments 280 References 280 9 Metal Complexes in Reverse Micelles 301 Marc A. Walters 9.1 Introduction 301 9.2 Location of Metal Complex Probes in the RM Core 302 9.3 Metal Complexes in Confinement 304 9.3.1 Substitution Reactions and Physical Methods 304 9.3.2 Redox Reactions in Reverse Micelles 309 9.3.3 Metal Ion Binding 311 9.4 Conclusions 320 References 320 10 Heterogenized Catalysis on Metals Impregnated Mesoporous Silica 323 Fatima Abi Ghaida, Sebastien Clement, and Ahmad Mehdi 10.1 Introduction 323 10.2 Mesoporous Silica in Catalysis 327 10.3 Modified Mesoporous Silica 329 10.4 Recent Advances in SBA Applied to Catalysis 332 10.5 Conclusion 341 References 342 Index 351
Este título pertence ao(s) assunto(s) indicados(s). Para ver outros títulos clique no assunto desejado.
List of Contributors xiii 1 Silanols as Building Blocks for Nanomaterials 1 Masafumi Unno and Hisayuki Endo 1.1 Introduction 1 1.2 Synthesis and Applications of Silanols 2 1.2.1 Silanetriols and Disiloxanetetraols 2 1.2.2 Cyclotetrasiloxanetetraol (Cyclic Silanols, All ]cis Isomer) 5 1.2.3 Cyclotetrasiloxanetetraol (Cyclic Silanols, Other Isomers) 14 1.2.4 Cyclotrisiloxanetriol 15 1.3 Structures and Properties of Nanomaterials Obtained from Silanols 20 1.3.1 Structure of Laddersiloxanes 20 1.3.2 Thermal Property of Laddersiloxanes 23 1.3.3 Thermal Property of Other Silsesquioxanes 26 1.3.4 Refractive Indices of Silsesquioxanes 28 1.4 Summary and Outlook 29 References 29 2 Biomacromolecule ]Enabled Synthesis of Inorganic Materials 33 Kristina L. Roth and Tijana Z. Grove 2.1 Introduction 33 2.2 DNA 34 2.3 Proteins and Peptides 36 2.3.1 Cage Proteins 37 2.3.2 Bovine Serum Albumin (BSA) 38 2.3.3 Engineered Peptides 40 2.3.4 Engineered Protein Scaffolds 42 2.4 Polysaccharides 44 2.5 Methods of Characterization 46 2.6 Conclusion 50 References 50 3 Multilayer Assemblies of Biopolymers: Synthesis, Properties, and Applications 57 Jun Chen, Veronika Kozlovskaya, Danielle Pretorius, and Eugenia Kharlampieva 3.1 Introduction 57 3.2 Assembly of Biopolymer Multilayers 58 3.2.1 Biopolymers and Their Properties 58 3.2.2 Growth and Thickness of Biopolymer Multilayers 59 3.2.3 Stability in Solutions and Enzymatic Degradation of Biopolymer Multilayers 74 3.2.3.1 Enzymatic Degradation 75 3.2.3.2 pH and Salt Stability 78 3.2.4 Hydration and Swelling of Biopolymer Multilayers 81 3.3 Properties of Biopolymer Multilayers 83 3.3.1 Surface Properties of Biopolymer Multilayers and Their Interaction with Cells 83 3.3.2 Antibacterial Properties 84 3.3.3 Immunomodulatory Properties 85 3.3.4 Mechanical Properties of Biopolymer Multilayers 87 3.3.5 Other Properties 90 3.4 Applications 91 3.5 Conclusion and Outlook 95 Acknowledgments 96 References 96 4 Functionalization of P3HT ]Based Hybrid Materials for Photovoltaic Applications 107 Michele Chevrier, Riccardo Di Ciuccio, Olivier Coulembier, Philippe Dubois, Sebastien Richeter, Ahmad Mehdi, and Sebastien Clement 4.1 Introduction 107 4.2 Design and Synthesis of Regioregular Poly(3 ]Hexylthiophene) 109 4.2.1 Metal ]Catalyzed Cross ]Coupling Reactions 114 4.2.1.1 Nickel ]Catalyzed Cross ]Coupling Reactions 114 4.2.1.2 Palladium ]Catalyzed Cross ]Coupling Reactions 121 4.2.2 Functionalization of P3HT 126 4.2.2.1 End ]Group Functionalization 127 4.2.2.2 Side ]Chain Functionalization 130 4.3 Morphology Control of P3HT/PCBM Blend by Functionalization 132 4.3.1 Introduction 132 4.3.2 End ]Group Functionalization 134 4.3.2.1 Fluorinated Chain Ends 135 4.3.2.2 Hydrophilic Chain Ends 139 4.3.2.3 Aromatic Chain Ends 139 4.3.2.4 Fullerene Chain Ends: Compatibilizer Case 141 4.3.3 Side ]Chain Functionalization 144 4.3.3.1 Thermal and Photo ]Cross ]Linking 144 4.3.3.2 Fullerene Side ]Functionalization on Polythiophene Block Copolymers 147 4.3.3.3 Cooperative Self ]Assembling 149 4.4 Polymer-Metal Oxide Hybrid Solar Cells 154 4.4.1 Anchoring Method 156 4.4.2 Surface Modification Using End ] and Side ]Chain ]Functionalized P3HT 158 4.4.2.1 End ]Group Functionalization 158 4.4.2.2 Side ]Chain Functionalization 161 4.5 Conclusion 163 Acknowledgments 164 References 164 5 Insights on Nanofiller Reinforced Polysiloxane Hybrids 179 Debarshi Dasgupta, Alok Sarkar, Dieter Wrobel, and Anubhav Saxena 5.1 Properties of Silicone (Polysiloxane) 179 5.2 Nanofiller Composition and Chemistry 183 5.2.1 Fumed Silica 183 5.2.2 Aerogel Silica 185 5.2.3 Carbon Black 187 5.3 Polymer [Poly(dimethylsiloxane)]-Filler Interaction 187 5.4 Polymer- Filler Versus Filler-Filler Interactions 190 5.5 PDMS Nanocomposite with Anisotropic Fillers 194 5.6 PDMS- Molecular Filler Nanocomposite 196 Acknowledgment 198 References 198 6 Nanophotonics with Hybrid Nanostructures: New Phenomena and New Possibilities 201 Noor Eldabagh, Jessica Czarnecki, and Jonathan J. Foley IV 6.1 Introduction 202 6.2 Theoretical Nanophotonics 204 6.2.1 Mie Theory for Spherical Nanostructures 205 6.2.2 Transfer Matrix Methods for Planar Structures 208 6.2.3 The Finite ]Difference Time ]Domain Method 214 6.2.4 The Discrete Dipole Approximation 215 6.3 Hybrid Nanostructures 216 6.3.1 Emergent Electrodynamics Phenomena: Inhomogeneous Surface Plasmon Polaritons 216 6.3.2 Advancing Imaging Beyond the Diffraction Limit with ISPPs 220 6.3.3 Emergent Material ]Dependent Optical Response in Hybrid Nanostructures 222 6.3.4 Perspective on the Horizon of Health Applications of Hybrid Nanostructures 228 6.3.5 Photodynamic Therapy 228 6.3.6 In Vivo Light Sources 231 6.4 Concluding Remarks 233 References 233 7 Drug Delivery Vehicles from Stimuli ]Responsive Block Copolymers 239 Prajakta Kulkarni and Sanku Mallik 7.1 Introduction 239 7.2 Block Copolymers for Drug Delivery 241 7.3 Polymeric Nanoparticles 241 7.3.1 Micelles 241 7.3.2 Hydrogels 243 7.3.3 Polymersomes 244 7.4 Stimuli ] Responsive Drug Delivery 245 7.4.1 Physical/External Stimuli ]Responsive Polymers 246 7.4.1.1 Temperature 246 7.4.1.2 Electro ]Responsive Polymers 247 7.4.1.3 Light ]Responsive Polymers 247 7.4.1.4 Ultrasound ]Responsive Polymers 248 7.4.2 Chemical/Internal Stimuli ]Responsive Polymers 248 7.4.2.1 PH ]Responsive Polymers 248 7.4.2.2 Ionic Strength ]Responsive Polymers 251 7.4.2.3 Enzyme ]Responsive Polymers 251 7.4.2.4 Reduction ]Sensitive Polymers 251 7.5 Challenges and Prospects 252 7.6 Summary 252 References 253 8 Mechanical Properties of Rubber ]Toughened Epoxy Nanocomposites 263 B. Zewde, I. J. Zvonkina, A. Bagasao, K. Cassimere, K. Holloway, A. Karim, and D. Raghavan 8.1 Introduction 263 8.2 Epoxy Resins 265 8.3 Rubber ] Toughened Epoxy Resin 266 8.4 Nanoparticle Filled Epoxy Nanocomposites 269 8.5 Carbon Nanotubes 270 8.6 Rubber ]Toughened CNT Filled Epoxy Nanocomposites 275 8.7 Nanoclay Filled Epoxy Nanocomposites 277 8.8 Rubber ]Toughened Nanoclay Filled Epoxy Nanocomposites 282 8.9 Silicon Dioxide Nanoparticles 284 8.10 Rubber ]Toughened Nanosilica Filled Epoxy Nanocomposites 286 8.11 Conclusions 289 Acknowledgments 280 References 280 9 Metal Complexes in Reverse Micelles 301 Marc A. Walters 9.1 Introduction 301 9.2 Location of Metal Complex Probes in the RM Core 302 9.3 Metal Complexes in Confinement 304 9.3.1 Substitution Reactions and Physical Methods 304 9.3.2 Redox Reactions in Reverse Micelles 309 9.3.3 Metal Ion Binding 311 9.4 Conclusions 320 References 320 10 Heterogenized Catalysis on Metals Impregnated Mesoporous Silica 323 Fatima Abi Ghaida, Sebastien Clement, and Ahmad Mehdi 10.1 Introduction 323 10.2 Mesoporous Silica in Catalysis 327 10.3 Modified Mesoporous Silica 329 10.4 Recent Advances in SBA Applied to Catalysis 332 10.5 Conclusion 341 References 342 Index 351
Este título pertence ao(s) assunto(s) indicados(s). Para ver outros títulos clique no assunto desejado.
