Instructor's Guide and Solutions Manual to Organic Structures from 2D NMR Spectra

Instructor's Guide and Solutions Manual to Organic Structures from 2D NMR Spectra

Field, L. D.; Li, H. L.; Magill, A. M.

John Wiley & Sons Inc

05/2015

392

Mole

Inglês

9781119027256

15 a 20 dias

The derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all Universities. Over recent years, a number of powerful two-dimensional NMR techniques (e.g.
Preface ix Solutions Summary 1 Problem 1 (1-iodopropane) 7 Problem 2 (2-butanone) 11 Problem 3 (2-hexanone) 15 Problem 4 (ethyl propionate) 19 Problem 5 (ethyl 3-ethoxypropionate) 23 Problem 6 (4-acetylbutyric acid) 28 Problem 7 (3-ethoxypropionyl chloride) 32 Problem 8 (ethyl 3-chloropropionate) 36 Problem 9 (isoamyl acetate) 40 Problem 10 (trans-4-hexen-3-one) 45 Problem 11 (trans-2-octen-4-one) 50 Problem 12 (3-nitrobenzaldehyde) 55 Problem 13 (3-iodotoluene) 61 Problem 14 (8-hydroxy-5-nitroquinoline) 64 Problem 15 (2-bromo-3-picoline) 69 Problem 16 (trans-anethole) 72 Problem 17 (cis-2-pentene) 75 Problem 18 (p-tolyl benzoate) 79 Problem 19 (phenyl p-toluate) 86 Problem 20 (4-biphenylyl acetate) 93 Problem 21 (4'-phenoxyacetophenone) 99 Problem 22 (4'-tert-butylacetophenone) 106 Problem 23 (2,2,4'-trimethylpropiophenone) 110 Problem 24 (trans-2-methyl-3-phenyl-2-propen-1-ol) 114 Problem 25 (methyl 4-ethoxybenzoate) 119 Problem 26 (methyl 3-(p-tolyl)propionate) 123 Problem 27 (4-(4'-methoxyphenyl)-2-butanone) 127 Problem 28 (ethyl 6-bromohexanoate) 132 Problem 29 (piperonal) 135 Problem 30 (cis-3-hexenyl benzoate) 139 Problem 31 (trans-2,cis-6-nonadienal) 146 Problem 32 (allyl glycidyl ether) 155 Problem 33 (3,4-epoxy-4-methyl-2-pentanone) 159 Problem 34 (dl-methionine) 162 Problem 35 (N-acetyl-l-leucine) 165 Problem 36 (isoamyl valerate) 170 Problem 37 ((E)-4-methyl-4'-nitrostilbene) 173 Problem 38 (2-tert-butyl-6-methylphenol) 181 Problem 39 (2-allyl-6-methylphenol) 186 Problem 40 (2-hydroxy-4-methoxybenzaldehyde) 194 Problem 41 (2'-hydroxy-5'-methylacetophenone) 198 Problem 42 (3'-fluoro-4'-methoxyacetophenone) 203 Problem 43 (trans-ferulic acid) 209 Problem 44 (sec-butyl 3-hydroxycinnamate) 215 Problem 45 (1-benzosuberone) 221 Problem 46 (dimethyl (3-bromopropyl)phosphonate) 228 Problem 47 (caffeine) 233 Problem 48 (benzyloxypropionitrile) 238 Problem 49 (cineole) 242 Problem 50 (thymoquinone) 246 Problem 51 (4-bromo-1-indanol) 251 Problem 52 (1-bromo-4-methylnaphthalene) 257 Problem 53 (carvacrol) 264 Problem 54 (acetoacetanilide) 272 Problem 55 (ethyl acetamidocyanoacetate) 277 Problem 56 ( -humulene) 283 Problem 57 (3,4-dihydro-2H-benzopyran-3-carboxylic acid) 289 Problem 58 (quinidine) 296 Problem 59 (salbutamol) 312 Problem 60 (2-hydroxy-1-naphthaldehyde) 322 Problem 61 (6-methyl-4-chromanone) 329 Problem 62 (citronellal) 336 Problem 63 ((+)-cis-2-oxabicyclo-[3.3.0]oct-6-en-3-one) 344 Problem 64 (melatonin) 349 Problem 65 (carvone) 362 Problem 66 (haloperidol) 370
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